This innovation can improve accurate long-term measurement of ion concentrations in applications such as environmental monitoring, precision agriculture and diagnostics for personalized healthcare. This is possible because the new sensor and supporting components are integrated into a unified chip. It’s small enough to be embedded into other devices, for example activity trackers used to monitor health and fitness.
The sensor is an industry first according to Imec and, and thanks to the SoC (system on chip) integration, it enables massive and cost-effective deployments in Internet-of-Things (IoT) settings. Its innovative electrode design results in a similar or better performance compared to today’s standard equipment for measuring single ion concentrations and allows for additional ion tests.
Sensors based on ion-selective membranes are considered the gold standard to measure ion concentrations in many applications, such as water quality, agriculture, and analytical chemistry. They consist of two electrodes, the ion-sensitive electrode with the membrane (ISE) and a reference electrode (RE). When these electrodes are immersed in a fluid, a potential is generated that scales with the logarithm of the ion activity in the fluid, forming a measure for the concentration. However, the precision of the sensor depends on the long-term stability of the miniaturized RE, a challenge that has now been overcome.
“The common issue with such designs is the leaching of ions from the internal electrolyte, causing the sensor to drift over time,” stated Marcel Zevenbergen, senior researcher at imec/Holst Centre. “To suppress such leaching, we designed and fabricated an RE with a microfluidic channel as junction and combined it with solid-state iridium oxide (IrOx) and silver chloride (AgCl) electrodes fabricated on a silicon substrate, respectively as indicating electrodes for pH and Cl-. Our tests demonstrated this to be a long-term stable solution with the sensor showing a sensitivity, accuracy and response time that are equal or better than existing solutions, while at the same time being much smaller and potentially less expensive.”
“We are providing groundbreaking sensing and analytics solutions for the IoT,” stated John Baekelmans, Managing Director of imec in The Netherlands. “This new multi-ion sensor is one in a series that Holst Centre is currently developing with its partners to form the senses of the IoT. For each sensor, the aim is to leapfrog the current performance of the state-of-the-art sensors in a mass-producible, wireless, energy optimized and miniaturized package.”
Imec is a research and innovation hub in nano-electronics and digital technologies. It’s headquartered in Leuven, Belgium and also has distributed R&D groups at a number of Flemish universities, in the Netherlands, Taiwan, USA, China, and offices in India and Japan. Holst Centre is an independent open-innovation R&D centre that develops generic technologies for Wireless Autonomous Transducer Solutions and for Systems-in-Foil. Holst Centre was set up in 2005 by imec (Flanders, Belgium) and TNO (The Netherlands) with support from the Dutch Ministry of Economic Affairs and the Government of Flanders. It is located on High Tech Campus Eindhoven.